The heat treatment of the anthracene fraction of coal tar under pressure is considered. In the production of synthetic pitch, the duration of the process is varied from 10 to 80 min, at a temperature of 500°C and a pressure of 3 MPa. Kinetic data for the formation of γ and α1 fractions show that the polycondensation of the γ fraction is of second order, while the formation of the α1 ...
The HallHéroult electrolysis process is the major production route for primary aluminium. An electrolytic cell is made of a steel shell with a series of insulating linings of refractory materials. ... Anodes are also made of petroleum coke, mixed with coaltarpitch, followed by forming and baking at elevated temperatures. The quality of ...
The construction and operation of granulation systems for coal pitch at OAO AltaiKoks is considered. Such systems improve the storage and transportation of coal pitch. Coal pitch is produced by processing coal tar at coke plants. Given that the coking of 1 t of coal batch yields ~40 kg of tar, which, in turn, will be converted to about 20 kg ...
Therefore, coal tar pitch (CTP), a byproduct of the coal tar distillation process, is an abundant source for the production of syngas and carbon nanomaterial due to its polycyclic aromatic hydrocarbons (PAH) composition [36, 37].
Detailed Description. Coal tar is a byproduct of the coking, liquefaction, or gasification of coal. Coaltar pitch is the residue that remains after the distillation of coal tar. Coal tar and coaltar pitch are used in coaltarbased sealcoat products, although use of coaltar pitch is more common than use of coal tar. Both coal tar and coal ...
The coaltarpitch is the most recognized binder for the anode production due to its good interaction with the coke particles at the mixing stage. It is able to wet the surface of coke particles and penetrate inside their open pores, transforming the dry particles into a paste amenable to be formed to the required shape [14].
The behaviour of mixtures of an impregnating coaltar pitch and a petroleum pitch during the early stages of ... Nowadays many research groups are focusing on ways to reduce production costs by searching for simplified processes or cheaper raw sources. ... Molecular dynamic simulation on the oxidation process of coal tar pitch. Fuel, Volume 242 ...
The production of coal tar pitch, as in the case of petroleum pitch, has likewise declined significantly over the past two decades. Coal tar pitch is a byproduct of metallurgical grade coke (metcoke) production. ... {osti_887333, title = {PRODUCTION OF CARBON PRODUCTS USING A COAL EXTRACTION PROCESS}, author = {Dadyburjor, Dady and Biedler ...
The carbonization of coal to produce metallurgical coke in slottype recovery ovens is the main source of coal tar production. But tar is not a prime process target, and its composition and properties are subordinated to the primary aim of producing metallurgical coke. ... QI is the most condensed fraction of all, and in the pitchforming ...
Later, in 1963, W. Watt developed a process for production of carbon fiber at Royal Aircraft Establishment which was patented by US Ministry of Defence. ... Different modification methods are herein discussed before moving on to fiber making process from coal tar pitchbased precursor. Final goal of these modification process is to produce ...
Pitch, on the other hand, typically has high aromatic content with low H:C ratios. For coal, the H:C ratio is intermediate, as is its aromatic content. Coals have higher density and molecular weight, and their unit structure has a more complex and diverse hydrocarbon structure compared with tar and pitch ( Figure 3 A).
The whole formed coke production process involving phenolic resin's preparation, their blending, coal tar pitch preparation and blending it with the phenolic resins blend, coke breeze grinding, mixing the blended binder with the coke breeze, briquetting, curing the green briquettes and carbonizing the cured briquettes at different temperatures, are illustrated in Fig. 1.
Coal tar is a thick dark liquid which is a byproduct of the production of coke and coal gas from coal. It is a type of has both medical and industrial uses. Medicinally it is a topical medication applied to skin to treat psoriasis and seborrheic dermatitis (dandruff). It may be used in combination with ultraviolet light therapy. Industrially it is a railroad tie preservative and ...
The purpose of this study is to develop a cocarbonization agent of coal pitch that can promote the formation of highquality mesophase pitch. 2. Raw materials. The refined pitch was prepared from coal tar pitch by removing quinoline insoluble in our groups. And the refined pitch was named RCTP.
The coal volatiles are collected and processed as various salable products. The basic process has been evaluated at the pilot scale and is ready for commercial application. It is envisioned that highquality coal tar pitch can be produced directly from the process, avoiding costly postprocessing of tar which is the common practice.
Therefore, the refining processes are designed to produce only the most valuable compounds. The first step in refining coal tar is distillation to get three different liquid parts, or "fractions," of the tar and an undistillable residue called pitch. About 5 percent of the tar distills at temperatures up to 410° F (210° C).
Production of coal tar pitch. Coal tar pitch is currently produced from coal tar, which is a byproduct of high temperature coking of coal in the manufacture of metallurgical coke. ... This process involves thermal oxidative condensation and subsequent thermal treatment and distillation until the pitch reaches the desired softening point (Fig 1).
Worldwide, 17 million ta −1 of coaltar are obtained as a by product in the chamber coking process for the production of metallurgical coke. Refining of this aromatic raw material yields coaltar pitch which is the traditional coalderived starting material for the manufacture of carbon precursors and carbon artefacts.
mediumpitch; hard pitch. 1. Introduction Coal tar pitch is a mixture of high molecular weight poly cyclic aromatic compoundsobtained as a residue from the distillation of coal tar. It is used as a binder in the production of anode for aluminium and electrode for graphite industries. Demandfor quality pitch has gone up with the advancementof the ...
Coal tar pitch (CTP) is abundant and widely used, but its properties will be affected due to oxidation aging during storage. In this study, CTP was oxidized by simulating the air oxidation process, and the change of chemical structure has been analyzed by Fourier transform infrared spectroscopy (FTIR), Xray diffraction (XRD), and both gas chromatography and mass spectrometry (GCMS).
Coal tar pitch with the advantages of low price, lower impurity content and the same elementary composition as coke is the most commonly used binder for the production of briquettes from coke breeze. However, coal tar pitch has little cohesiveness before being heated to melting state and the carbonization must be operated at high temperature ...
In paper [87], the ethylene tar pitch containing significant amounts of reactive unsaturated hydrocarbons is modified by the introduction of coal tar pitch in an amount of 3050 wt%. When the ethylene tar pitch is coked separately, an isotropic mesophase is formed, unfavourable for the production of needle coke [88] .
The use of petroleum and coal tar pitch as an inexpensive raw material to produce CNMs is a possible solution to this problem Li et al., (2021a); Jiang et al., ... For example, the use of mesophase pitch leads to a significant increase in price due to the extremely complex process of its production and low yield (about 10 wt.%). Although modern ...
The properties of the carbon materials obtained as the final product of coal tar pitch carbonization process are a consequence of the type of chemical and physical phenomena occurring through the process. A new simplified approach for modeling of the primary carbonization is presented to provide the semiquantitative knowledge about the process useful for improving the efficiency of the ...
The CTP (coal tar pitch) and CPC (calcined petroleum coke) raw materials used for anode production are both manufactured from byproducts of other industries making the aluminum industry dependent on others for two key raw materials. Despite this, the industry has made steady improvements in anode quality and performance over the last 50 years.
Manufacturing process Coal tar is obtained by cooling the gas that ... production of these aromatic chemicals was derived from the petrochemical industry, and ... 1987, 2010) coaltar pitch and roofingtar emissions were found to be mutagenic in Salmonella typhimurium ...
The whole formed coke production process involving air blown coal tar pitch preparation, its blending with molasses containing hardeners, such as ammonium carbonate, ammonium nitrate and nitric acid of varying amount, and mixing the binder with ground anthracite fines or coke breeze, briquetting and. Results and discussion
The process of manufacturing coaltar pitch from a coaltar obtained by distillation of coal in a fluidized bed; comprising the steps of forming a mixture at a temperature of 100 C. of equal weights of anthracene oil and said coaltar, and distilling said mixture under a pressure of 18 mm. of mercury until the residue reaches a K. S. softening ...
Abstract. Worldwide, 17 million ta −1 of coaltar are obtained as a by product in the chamber coking process for the production of metallurgical coke. Refining of this aromatic raw material yields coaltar pitch which is the traditional coalderived starting material for the manufacture of carbon precursors and carbon artefacts.
The whole formed coke production process involving air blown coal tar pitch preparation, its blending with molasses containing hardeners, such as ammonium carbonate, ammonium nitrate and nitric acid of varying amount, and mixing the binder with ground anthracite fines or coke breeze, briquetting and curing the green briquettes, carbonizing the cured briquettes at different temperatures, and ...
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